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The rapid growth
of the hi-tech technologies allows solving the ensemble of the problems, which
appear due to influence of the economic laws on purposes and problems of the industry.
Amongst collection
of the hi-tech technology, there are some of the most attractive and
perspective, from the economic and technical standpoints. Amongst them there
are technologies of precision grown of a heterostructures - molecular-beam
epitaxion (MBE) and chemical vapor deposition (CVD).
These technologies
have allowed proceed with creation laminated heterostructures with sharp
interface and size of the active areas comparable to wavelength of the
electron. Heterostructure (the film) in fact is a monocrystal, in which is
inserted layer, diversified by chemical composition from composition of the
matrix.
MBE and CVD became
essential booster of the work on making the row of instruments of the rapidest electronics.
For instance, we can take the technologies of the creation hardware components in
IT industry. It’s known, that in needs of the processing bigger volume of information
in more short time brings about unceasing complication of the integral schemes
and increasing of the speed of each separate element. The traditional way of the
speed increasing - a reduction of the sizes and increasing the density of the
packing becomes all more not efficient, is since reached all more expensive
price. Besides this, there are some limits of the elements reduction, which
depends from technological and physical restrictions. In such conditions, absolutely
obvious way of the speed increasing is an increase the velocities of the
carriers. Turned out to be that, only use of the films, which built on MBE and
CVD technologies, has allowed realize this in real tools.
As it was already
noticed, there are two main methods and two types of the equipment, which with
equal success are used for films making.
Chemical vapor deposition (CVD). In reactor, which has rather complex installation are
located several substrates (be-that GaAs, saphire or something else). The substrates
(the circles) - such thin cuts of the monocrystal, to which flow "thundering
mixture" (complex, usually powerfully combustible) and under high
temperature makes a reaction with substrates. As a result, layers shaping of
the film occur - a layer of the molecules beside a layer of the molecules. With
this method, for instance, wide-zone semiconductors materials on GaN base are
grown (for example, structures for fabrication blue-green photodiode or that
the short-wave laser for new generation CD-ROM).
Other method is
MBE or molecular beam epitaxion. It is based on high-vacuum installation, which
has a big sizes and according to this it is possible to dispose the enormous
amount of the substrates. From special parts
molecular flow gets on substrate. It can be modulated with a special damper,
and this allow on surfaces of the substrate film grow.
The most
wide-spread in present time are CVD systems (fig. 1), which unite in itself voluminous
collection of sub-technologies (LPCVD, APCVD, MCVD, ESAVD, MOCVD), which quantity
grows, as result of the influence and combinations of other physico-chemical
technologies with CVD technology.
By
means of CVD technology big amount varied laminated films is produced. |
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Earlier science
and technology were oriented on thermal actuated CVD process. But, new start of
the direction in plasma actuated processes was recently realized.
This is connected
with that, that presently whole technology is orientated on low level
temperature processes. It is joined with need of the improvement quality of the
films. Diffusion is excluded in such low level temperature process.
In some CVD
processes gaseous precursors are traditionally used. However, at present time, liquid
precursors are often used instead of gaseous ones. The reason is physical
properties of liquid precursors. They are less harmful, flammable, corrosive
and poisonous than gases. On the base of liquid precursors one of the most
perspective CVD technologies (MOCVD) is developing. MOCVD is a
metalorganic chemical vapor deposition, which had extremely development at the
last 10 years.
Special question,
which has to be described more wide, is precursor
delivery into reactor.
There are several
technologies of precursor delivery into reactor. Amongst them, there are two
main technologies: bubbler delivery system and direct liquid injection.
The first of precursor delivery
methods into reactor is a bubbler delivery
system. |
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Essence of this method is concluded in following. The
vapor is obtained and then transported through heated gas lines into the
reactor. The flow of vapor is directly related to the vapor pressure in the
container, which varies with temperature, according to the characteristics of
the liquid. Main fault of bubbler systems is the sensitivity to temperature
and, as result, poor reproducibility and instability of the vapor flow. There
are two basic configurations of bubblers: with and without carrier gas.
In configurations without using a carrier gas the
resulting flow of vapor depends from vapor-pressure characteristics, i.e. on
temperature of precursor. But many complex precursor sources change their
evaporation rates when heated over an extended period of time and generally can
break down. Other bubbler system configurations use a carrier gas and operate
by bubbling a carrier gas through a temperature controlled liquid.(Fig. 2)
There is formation of small bubblers of carrier gas in the liquid, in which
vapor quickly attains its equilibrium vapor pressure as the bubbles float to
the liquid surface. The amount of vapor delivered is determined by carrier gas
flow and the temperature of the liquid. Temperature control is critical and
indispensable for accurate vapor delivery even when the nominal liquid
temperature is set at room temperature. Although there are many sophisticated
bubbler systems with accurate and reproducible vapor delivery and many other
improvements, temperature control remains critical.
The second precursor delivery method is a direct liquid injection (DLI).
DLI system has many benefits,
when we compare it with bubbler delivery system. It provides accurate, stable
control of precursor delivery rate. Temperature control is much less critical
as for the bubbler systems. With a suitable solvent, a variety of precursor
compounds can be used, including solids and other compounds not suitable for
vapor delivery. |
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Direct liquid injection systems can be made by 2 ways.
First of them is using pumps (piston in cylinder) for liquids
control displacement. In such method for avoiding interruption of the flow
while refilling the cylinder, two cylinders are used. The liquid can mix with
the carrier gas prior to streaming to the evaporator, but more attractive is
the following way: the liquid flows to evaporator through which flows carrier
gas. This ensures heating of the liquid
and evaporation into the carrier. The amount of vapor delivered is not
sensitive to the exact temperature of the evaporator. It is really difficult to
make the liquid injection system in which two cylinders exactly matched. That’s
why there are a lot of advanced systems (e.g. dual-piston micro-stepper motor
driven metering pump which delivers liquid in a smooth pulse-free manner).
Second way is using of a
thermal mass flow controller which can be used for liquids just for a gas and
can measure liquid flow. The liquid, controlled by the mass flow controller, is
typically pressurized to flow to the evaporator using a carrier gas.
Temperature and pressure are only boundary conditions. The only criterion is
that the partial pressure of the fluid must be lower than the vapor pressure at
that temperature to prevent condensation. Such systems need a minimum flow of
gas to carry the liquid into the heated evaporation zone. Flows are stable,
repeatable and easily adjustable via the mass flow controllers.
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Amongst collection
of the hi-tech technology, there are some of the most attractive and
perspective, from the economic and technical standpoints. Amongst them there
are technologies of precision grown of a heterostructures - molecular-beam
epitaxion (MBE) and chemical vapor deposition (CVD).
These technologies
have allowed proceed with creation laminated heterostructures with sharp
interface and size of the active areas comparable to wavelength of the
electron. Heterostructure (the film) in fact is a monocrystal, in which is
inserted layer, diversified by chemical composition from composition of the
matrix.
MBE and CVD became
essential booster of the work on making the row of instruments of the rapidest electronics.
For instance, we can take the technologies of the creation hardware components in
IT industry. It’s known, that in needs of the processing bigger volume of information
in more short time brings about unceasing complication of the integral schemes
and increasing of the speed of each separate element. The traditional way of the
speed increasing - a reduction of the sizes and increasing the density of the
packing becomes all more not efficient, is since reached all more expensive
price. Besides this, there are some limits of the elements reduction, which
depends from technological and physical restrictions. In such conditions, absolutely
obvious way of the speed increasing is an increase the velocities of the
carriers. Turned out to be that, only use of the films, which built on MBE and
CVD technologies, has allowed realize this in real tools.
As it was already
noticed, there are two main methods and two types of the equipment, which with
equal success are used for films making.
Chemical vapor deposition (CVD). In reactor, which has rather complex installation are
located several substrates (be-that GaAs, saphire or something else). The substrates
(the circles) - such thin cuts of the monocrystal, to which flow "thundering
mixture" (complex, usually powerfully combustible) and under high
temperature makes a reaction with substrates. As a result, layers shaping of
the film occur - a layer of the molecules beside a layer of the molecules. With
this method, for instance, wide-zone semiconductors materials on GaN base are
grown (for example, structures for fabrication blue-green photodiode or that
the short-wave laser for new generation CD-ROM).
Other method is
MBE or molecular beam epitaxion. It is based on high-vacuum installation, which
has a big sizes and according to this it is possible to dispose the enormous
amount of the substrates. From special parts
molecular flow gets on substrate. It can be modulated with a special damper,
and this allow on surfaces of the substrate film grow.
The most
wide-spread in present time are CVD systems (fig. 1), which unite in itself voluminous
collection of sub-technologies (LPCVD, APCVD, MCVD, ESAVD, MOCVD), which quantity
grows, as result of the influence and combinations of other physico-chemical
technologies with CVD technology.
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